Wash and quarter the peppers and remove the white inner skins and seeds. Place with the cut surface facing down on a baking sheet lined with aluminum foil.
Bake in a hot oven at 225 ° C for about 30 minutes. The peel should darken slightly and start to bubble. Take out of the oven, cover the pods with a damp towel and, one by one, remove the skin from the pods with a knife.
Tip: If you have a microwave, it is a little more convenient. Prepare the peppers as above, place them on a plate and cook for about two and a half to three minutes on the highest setting. Then peel off the skin.
Peel and chop the garlic and make a marinade with the balsamic vinegar, white wine, olive oil, salt and pepper.
Tip: If you like it, you can stir in finely chopped basil.
Mix this marinade well with the peppers and let it steep for a few hours.
Since various types of Italian antipasti are served, I have specified the number of people as 12.
This starter goes well with other marinated vegetables, crostini (e.g. with tomatoes), Parma ham with melon, etc.